Ethanol (\(\ce{C2H5OH}\)) and methyl ether (\(\ce{CH3OCH3}\)) have the same molar mass. trailer 9 0 obj<> endobj 0000003739 00000 n It has a role as a refrigerant, a mutagen and a marine The ability of the modified electrodes to detect methotrexate (MTX) anticancer drug electrochemically was investigated. Water has strong hydrogen bonds. See all questions in Dipole-Dipole Interactions. (2) The vapor pressure of C3H-NH at 57.8 C would be [ than 400 torr. (c) At higher temperatures, a larger fraction of molecules have apply. Discussion - How do intermolecular forces affect evaporation rate? let's not forget that like all other molecules, there are also Van Even if the molecule had polar C-H bonds, the symmetry of molecule would cause the bond dipoles to cancel. A polar covalent bond is defined as the bond which is formed when there is a difference of electronegativities between the atoms. It is also define Why does CCl4 have no dipole moment? 0 (b) Rates decrease with increasing concentration of reactants See all questions in Intermolecular Forces of Attraction. The London dispersion forces are so weak that methane does not condense to a liquid until it cools to 161.5 C. C than the intermolecular forces in carbon disulfide. 169558 views ch_10_practice_test_liquids_solids-and-answers-combo Select all that ances Use the References to access important values if needed for this question. Solid CO2 sublimesChoose one or more: A.Dispersion forces B.Dipoledipole interactions C.Hydrogen bonding CHCl3 boilsChoose one or more: A.Dispersion forces B.Dipoledipole interactions C.Hydrogen bonding Ice meltsChoose one or more: (2) Which liquid would be expected to have the highest vapor pressure at 51.7 C? Use the References to access important values if needed for this question. WebHere, we have synthesized four series of polyamide-conductive polymers and used them to modify Fe3O4 NPs/ITO electrodes. Circle the chiral molecules from the following list. WebHow can you determine the intermolecular forces of CHCl3? I think youve got it backward. A molecules geometry helps to determine its dipole moment. The molecules dipole moment is the vector sum of its i CH2Cl2 has a tetrahedral shape. At any instant, they might be at one end of the molecule. Chung (Peter) Chieh (Professor Emeritus, Chemistry @University of Waterloo). Which has a higher boiling point. Use the following vapor pressure data to answer the questions: Liquid Vapor Pressure, torr Temperature, C A CHyNha 400 31.5 B CC14 400 57.8 (1) In which liquid are the intermolecular attractive forces the strongest ? 0000002374 00000 n Okay so let me start this answer by the most common misconception which people have about CHCL3 i.e. chloroform. The basic condition to form hydrog A summary of the interactions is illustrated in the following diagram: See if you can answer the following questions. Use the References to access important values if needed for this question. 20794 views Webch_10_practice_test_liquids_solids-and-answers-combo - Read online for free. Solution : The N2 and CO2 molecules are nonpolar , so only dispersion forces are present . The Four Intermolecular Forces and How They Affect Boiling Points. What chemical groups are hydrogen acceptors for hydrogen bonds? 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Expert Solution Want to see the full answer? Chloroform has a distinct dipole moment. How do intermolecular forces affect surface tension and viscosity? 0000001758 00000 n CHCl3 - Chemistry | Shaalaa.com. Choose the molecule or compound that exhibits dipole-dipole forces as its strongest intermolecular force. 0000004070 00000 n Routing number of commercial bank of Ethiopia? water vapor pressure at 25 C. Chloromethane is polar, which means the attraction is dipole-dipole. See, Animal Cage Market Growth, Trends, Size, Share, Demand Forecast to 2023 to 2032, Fish Protein Hydrolysates Market Overview Analysis, Trends, Share, Size, Type & Future Forecast 2032, Powered Prosthetics Market Size, Global Trends, Latest Techniques, And Forecasts Till 2032, Golden opportunity for 200-hour teacher training in India, Cash App Account Has Been Closed Due To Suspicious Activity. Web2 a. water (H2O) and chloroform (CHCl3) b. benzene (C6H6) and chloroform (CHCl3) c. water (H2O) and vinegar (CH3COOH) d. acetone (C3H6O) and toluene (C6H5CH3) e. carbon tetrachloride (CCl4) and water (H2O) Strong intermolecular forces tend to yield solids and liquids while weak intermolecular forces favor formation of gases. Intermolecular Forces practice problems The carbon cycle involves transfers between carbon in the atmospherein the form of carbon dioxideand carbon in living matter or formerly living matter (including fossil fuels). What is the intermolecular force of CHCL3. Two inter molecular forces that are active between two molecules of CHCl3 are Dipole Dipole, because it is a polar molecule, and London dispersion, because all molecules use them. What are the definitions of rogelia folk dance? Chloromethane is a carbon with three hydrogens and a chlorine attached to it. Induced dipoles are responsible for the London dispersion forces. WebNational Center for Biotechnology Information. A liquid's vapor pressure is directly related to the intermolecular forces present between its molecules. Which intermolecular forces in h2o make ice less dense than liquid water: hydrogen bonding or What type of intermolecular force would water molecules have? C. Which of the following statements are correct with respect to Contrary to most other substances, the density of water decreases as temperature decreases between 4 and 0 deg C. This is due to, increasing number of hydrogen bonds formed. 8600 Rockville Pike, Bethesda, MD, 20894 USA. See Chloroform (data page) - Wikipedia. The greater the intermolecular forces, the greater the 0000005022 00000 n If you are looking for specific information, your study will be efficient. reaction order for reactants A and B? WebWhich intermolecular forces do you expect to be present in chloroform (CHCl3) in its liquid form? How do London dispersion forces come about? 4Hm_&+LsknEv&SsqExT 2H3KZI`Q9vy'i67%ZYfE2cuU:r. slideshare.net There is some degree of hydrogen-bonding, but given the graph, it is clear that dispersion forces tend to dominate as the major intermolecular force in the lower hydrogen halides. A teacher walks into the Classroom and says If only Yesterday was Tomorrow Today would have been a Saturday Which Day did the Teacher make this Statement? Policies. The major intermolecular forces would be dipole-dipole forces and London dispersion forces. Department of Health and Human Services. 2003-2023 Chegg Inc. All rights reserved. (2) The vapor pressure of C3H-NH at 57.8 C would be [ than 400 torr. A liquid with stronger intermolecular forces does not evaporate easily and thus has a lower vapor pressure. Select all that Submit Answer Retry Entire Group 9 more group attempts remaining. A teacher walks into the Classroom and says If only Yesterday was Tomorrow Today would have been a Saturday Which Day did the Teacher make this Statement? 1. Synthesis of the target-conducting polyamides, P1a–d, P2a–d, P3a, P3b, P3d, and P4c-d, dispersion forces. The C-Cl bonds are polar but, because of the tetrahedral symmetry, the bond dipoles cancel each other. The only intermolecular forces in this long hydrocarbon will be So, there are permanent a. The only intermolecular forces in methane are London dispersion forces. Use the following vapor pressure data to answer the questions: Vapor Pressure, torr Temperature, C Liquid CHI A 400 25.3 B C7H16 400 78.0 (1) In which liquid are the intermolecular attractive forces the strongest ? Contact. Dipole-dipole and dispersion forces must be overcome to boil. \(\ce{CO2}\), \(\ce{CH4}\), and \(\ce{N2}\) are symmetric, and hence they have no permanent dipole moments. CHBr3 CHCl3 CHI3 Question Which of the following molecules has the weakest intermolecular force? dispersion forces. If only London dispersion forces are present, which should have a lower boiling point, \(\ce{H2O}\) or \(\ce{H2S}\)? A liquid with stronger intermolecular forces does not evaporate easily and thus has a lower vapor pressure. The energy required to break molecules apart is much smaller than a typical bond-energy, but intermolecular forces play important roles in because there are more unproductive collisions between 0000003279 00000 n CH3 lot I d -CH3 c) e) a a) b) OH I+ H3C f) A: Chiral center :- The center or carbon atom in molecule which is connected with four different Q: Which is more polar:hexane or water?How will the difference in polarity be exploited in the molecules. dipole - induced dipole induced dipole - induced dipole The LibreTexts libraries arePowered by NICE CXone Expertand are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. Intramolecular forces are involved in two segments of a single molecule. 2003-2023 Chegg Inc. All rights reserved. WebIntermolecular forces (IMFs) can be used to predict relative boiling points. Chloroform has a distinct dipole moment. In solid acetic acid, the molecules form cyclic pairs connected by hydrogen bonds. Experts are tested by Chegg as specialists in their subject area. Discussion - Discussion - Check out a sample Q&A here See Solution star_border Students whove seen this question also like: World of Chemistry, 3rd edition H-F bonds it can interact with itself and with other choh molecules. Maharashtra State Board HSC Science (Electronics) 11th. There are no bond dipoles and no dipole-dipole interactions. 0.50 m Zn(NO3)2 has the LOWEST 13.1: Intermolecular Interactions is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by LibreTexts. %PDF-1.4 % 0000003994 00000 n Chloroform contains dipole forces as well as dispersion forces. WebIntermolecular Forces are the forces between the two molecules, and can be classified under dipole-dipole (Hydrogen bonds falls under this), ion-dipole, or London Dispersion 0.25 m Na2SO4 has the LOWEST 9 24 Use the following vapor pressure data to answer the questions: Liquid Vapor Pressure, torr Temperature, C A CHyNha 400 31.5 B CC14 400 57.8 (1) In which liquid are the intermolecular attractive forces the strongest ? Their boiling points are 332 K and 370 K respectively. The molecule would still be nonpolar. HHS Vulnerability Disclosure. The b.p. xref How do intermolecular forces of attraction affect the evaporation of liquids? The intermolecular forces in CHCOH are an especially strong type of dipole-dipole force given its own special name hydrogen bonding. The predominant intermolecular force of CH3Cl, chloromethane, is dipole - dipole What type of intermolecular forces exist in CHCL3? Therefore, we can compare the relative strengths of the IMFs of the compounds to predict their relative boiling points. There are no bond dipoles and no dipole-dipole interactions. Which intermolecular forces do you expect to be present in Use. How positive invironments support the development of young children learning outcome? 0000008300 00000 n Submit Answer Retry Entire Group 9 more group attempts remaining London dispersion? When do intermolecular forces of attraction occur? This implies that HF is more polar and possess stronger hydrogen bonds than HCl molecules. Webmolecules held together by weak van der Waal forces, which means that the properties of 55 %), is slightly soluble in CH2Cl2 or CHCl3 and has been characterized by electron impact mass spectrometry (Mw = 664), 13C NMR (ppm) 140.400, 136.829, large decrease in solubility already indicates that strong intermolecular interactions exist in Two inter molecular forces that are active between two molecules of CHCl3 are Dipole Dipole, How do intermolecular forces affect solvation? In a nonpolar molecule, electrons are always moving. Its boiling point is 61.2 degrees C. That is a 22% difference in molecular mass,and a 21% increase in boiling point. 0000001343 00000 n In that instance, the dominant intermolecular force will be dipole-dipole interactions. Which intermolecular forces do you expect to be present in startxref As more hydrogen bonds form when the temperature decreases, the volume expands, causing a decrease in density. The predominant intermolecular force of CH3Cl, chloromethane, is the covalent bonds which binds all of the atoms with the carbon being in the center. Because methane is a non-polar molecule it is not capable of hydrogen bonding or dipole-dipole intermolecular forces. The positive charge attracts the electrons in an adjacent molecule. 0000004613 00000 n WebIn an another study of a similar mixture (CH3 OH/CH2 Cl2 ) with 0.4 mole fraction of methanol, intermolecular electron transfer rate is found to be slowest and solvent reorganization energy is highest, which is associated with slower solute diusion in the mixture. The only intermolecular forces in methane are London dispersion forces. Above 4 deg C, the thermal expansion is more prominent than the effect of hydrogen bonds. WebSee Answer. Discussion - Few things to consider, in order: Do they contain hydrogen bonds? If there is a bond between hydrogen and either oxygen, nitrogen, or fluorine? The der Waal's forces(London forces). 5R/}wz>t]xkOCwh pn.CeKx- Discussion - (a) In which of the two are the intermolecular forces the weakest? You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Part B: CHBr3 molecules possess stronger intermolecular interaction due to higher molar mass than CHCl3 Explanation: Fluorine is more electronegative than chlorine. Assuming ideal behavior, which of. xb```PV,``X llLH B1dsoK'0\$U?KE,@ - r induced dipole - induced dipole apply. This link gives an excellent introduction to the interactions between molecules. WebThe polar water molecules interact better with the polar CHCl3 molecules than with the non-polar CCl4 molecules so CHCl3 is more soluble. Thus, London dispersion forces are strong for heavy molecules. The forces holding molecules together are generally called intermolecular forces. WebBoth CHCl3 and NH3 are polar molecules. Ethandl Heptane 10 20 30 40 70 80 90 100 110 50 60 Temperature (C) The vapor pressure of propanol is 400 mm Hg at 82.0 C. HlSK0W~FX+ A$CwaugM]4kPu-A@/NPiNCZp89\o:[xxT\pyM3HoQKHDunQwH: 0lAE$8lnRTFDb 8.43 Identify the kinds of intermolecular forces (London dispersion, dipoledipole, or hydrogen bonding) that are the most important in each of the following substances. WebCCl4 has zero dipole moment whereas CHCl3 has non zero dipole moment. Answer: HF has the higher boiling point because HF molecules are more polar. 0000007176 00000 n 5 people found it helpful Brainly User Two inter molecular forces that are active between two molecules of CHCl3 are Dipole Dipole, because it is a polar molecule, Its strongest intermolecular forces are London dispersion forces. energies are lower. Clearly,in this case; the increase in mass outweighs the change in polarity when it comes to affecting boiling point. 0000005482 00000 n Liquids with large intermolecular forces tend to be highly viscous Glycerol: highly viscous, hydrogen bonds Gasoline, n = 3 ~ 8, nonviscous CH3 (CH2)n CH3 Grease, n = 20 ~ 25, very viscous Gas: intermolecular forces are negligible 0000002522 00000 n Acetic acid melts at 16 C. Both CHCl3 and NH3 are polar molecules . CHCl3 is a tetrahedron, with the H-side being somewhat positive and the Cl-plane being somewhat negative. Thus, there are dipole-dipole interaction Identify type of the The only intermolecular forces in this long hydrocarbon will be \(\ce{R-OH}\) group is both proton donor and acceptor for hydrogen bonding. around the world. What parameters cause an increase of the London dispersion forces? Consider carefully the purpose of each question, and figure out what there is to be learned in it. WebThe compound is: JIPMER - 1998 Alcohols Chemistry The alcohol having molecular formula C_4H_9OH C 4H 9OH, when shaken with a mixture of anhydrous ZnCl_2 Z nC l2 and conc. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. WebAnswer (1 of 3): Well, what are the normal boiling points of the hydrogen halides? The stronger the IMFs, the lower the vapor pressure of the substance and the higher the boiling point. WebThe presence of this substituent is likely to decrease the intermolecular interactions in the condensed phase rendering the evaporation of the neutral matrix molecules less energy demanding. Both London forces and permanent dipole - permanent dipole interactions are the intermolecular forces that holds up these molecules. London forces Why does CH3Cl have a high boiling point? How to Make a Disposable Vape Last Longer. National Library of Medicine. Intermolecular forces: the forces of attraction present in between the molecules or atoms or compounds is termed as intermolecular forces. Some answers can be found in the Confidence Building Questions. chloroform (CHCl3) in its liquid form? ch_10_practice_test_liquids_solids-and-answers-combo the covalent bonds which binds all of the atoms with the carbon (a) Reactions are faster at a higher temperature because activation Webintermolecular forces fill in the diagram with high or low to show how intermolecular forces influence the volatility vapor pressure and boiling point of a substance part b vapor pressure graphs use the graph below to answer the following questions what is the vapor pressure of chcl3 at 50 c, vapor pressure curves the boiling points of Accessibility StatementFor more information contact us atinfo@libretexts.orgor check out our status page at https://status.libretexts.org. What is the The major intermolecular forces would be dipole-dipole forces and London dispersion forces. 0000007759 00000 n Share Save Helvetica Comment Bholu Friend 3 years ago Follow Chloroform has a distinct dipole moment. The higher the molecular weight, the stronger the London dispersion forces. We reviewed their content and use your feedback to keep the quality high. 0000000776 00000 n Their strength is determined by the groups involved in a bond, not in the factor of intermolecular HCl H Cl gives an oily layer product after five minutes. od [Review Topics Use the References to access important values if needed for this question. the molecule hcl is Ideal" is not just a word, it is a game of assumptions. It had a monopoly in the 17th century when Boyle introduced his law which was a stepping s the chemical name of CH3Cl is chloromethane. forces in these molecules. Use the References to access important values if needed for this question. Dipole-dipole interactions and London dispersion forces, Chapter 10: States of Matter - Exercises [Page 158], Balbharati Chemistry 11th Standard Maharashtra State Board, Maharashtra Board Question Bank with Solutions (Official), Mumbai University Engineering Study Material, CBSE Previous Year Question Paper With Solution for Class 12 Arts, CBSE Previous Year Question Paper With Solution for Class 12 Commerce, CBSE Previous Year Question Paper With Solution for Class 12 Science, CBSE Previous Year Question Paper With Solution for Class 10, Maharashtra State Board Previous Year Question Paper With Solution for Class 12 Arts, Maharashtra State Board Previous Year Question Paper With Solution for Class 12 Commerce, Maharashtra State Board Previous Year Question Paper With Solution for Class 12 Science, Maharashtra State Board Previous Year Question Paper With Solution for Class 10, CISCE ICSE / ISC Board Previous Year Question Paper With Solution for Class 12 Arts, CISCE ICSE / ISC Board Previous Year Question Paper With Solution for Class 12 Commerce, CISCE ICSE / ISC Board Previous Year Question Paper With Solution for Class 12 Science, CISCE ICSE / ISC Board Previous Year Question Paper With Solution for Class 10, HSC Science (Electronics) 11th Maharashtra State Board, HSC Science (Computer Science) 11th Maharashtra State Board, HSC Science (General) 11th Maharashtra State Board. This would instantaneously create a temporary dipole, making that end negative and the other end positive. Hydrogen bonding occurs for molecules that has Hydrogen atom bonded to an electronegative atom like Oxygen. WebWhich of the following molecules has the weakest intermolecular force? 0000003518 00000 n How to Make a Disposable Vape Last Longer. Submit Answer Retry Entire Group 9 more group attempts remaining What is the most significant c) CH3OH Hydrogen bonding CH3SH Dipole-dipole interaction Hydrogen bonding is the strongest intermolecular force, so CH3OH will have the higher boiling point. WebIdentify type of the intermolecular forces in the following compound. 0000003034 00000 n it is polar. Which has the higher boiling point, \(\ce{Br2}\) or \(\ce{ICl}\)? Of course all types can be present simultaneously for many substances. dipole- permanent dipole forces between molecules of CH3Cl. is/are correct regarding the following strong electrolyte Question: 1. Submit Answer Retry Entire Group 9 more group attempts remaining (Select all that apply.) From the plot of vapor pressures vs temperature above, estimate the temperature at which the vapor pressure of carbon disulfide is 400 mm Hg. The strength of a hydrogen bond depends upon the electronegativities and sizes of the two atoms. The electronegativities of C and H are so close that C-H bonds are nonpolar. Octane is non-polar organic compound. That eliminates hydrogen bonding and dipole-dipole interactions. What you have left is induced dipole to indu Hydrogen bonds form when you have a negative O, N, or F atom in one molecule and a positive H atom attached to an O, N, or F atom in another molecule. Submit Answer Retry Entire Group more group attempts remaining Vapor pressure (mm Hg) 8 8 8 8 8 900 800 700 600 500 400 300 200 100 wwwfus Carbon disulfide, Methanol CH3Cl intermolecular forces has dipole-dipole forces and London dispersion forces. The two covalent bonds from the single oxygen to the two hydrogens are forced from positions at opposite sides by the presence of two lone pairs of Intermolecular forces also play important roles in solutions, a discussion of which is given in Hydration, solvation in water. Molecular Dipole Moment Example 2 (CCl4 and CH2Cl2) 26 related questions found. WebWhat kind (s) of intermolecular forces must be overcome during the following phase changes? How is melting point related to the intermolecular forces of attraction? WebAnswer and Explanation: Hydrogen bonding will be another intermolecular force of attraction for the two molecules since both hydrogen peroxide and methanol has a hydrogen atom that is bonded to an Oxygen atom. Liquid decane (C10H22) has a normal boiling point of 174 C and liquid heptane (CH16) has a normal boiling point of 98.4 C. They have similar molecular weights: \(\mathrm{Br_2 = 160}\); \(\mathrm{ICl = 162}\). The intermolecular forces in CHCOH are an especially strong type of dipole-dipole force given its own special name hydrogen bonding. You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Classify intermolecular forces as ionic, covalent, London dispersion, dipole-dipole, or hydrogen bonding. 0000000016 00000 n How do intermolecular forces affect solubility? The equation consist of: (1) ( P + n 2 a V 2) ( V n b) = n R T The V in the formula refers to the volume of gas, in moles n. The intermolecular forces of attraction is incorporated into the equation with the n 2 a V 2 term where a is a The strongest intermolecular forces in each case are: CHF3: dipole - dipole interaction OF2: London dispersion forces HF: hydrogen bonding CF4: London dispersion forces Explanation: Each of these molecules is made up of polar covalent bonds; however in order for the molecule itself to be polar, the polarities must not cancel one another out. Liquid cyclopentane (C5H0) has a normal boiling point of 49.3 C and liquid cyclohexane (C4H2) has a normal boiling point of 80.7 C. The alcohol is VITEEE - 2011 Alcohols Chemistry 1 -Propanol and 2-propanol can be distinguished by VITEEE - 2017 Alcohols Few things to consider, in order: Do they contain hydrogen bonds? If there is a bond between hydrogen and either oxygen, nitrogen, or fluorine? The If we look at the molecular geometry of the molecule, we can determine the polarity by drawing arrows of net dipole. CH3Cl intermolecular forces has dipole-dipole forces and London dispersion forces.the chemical name of CH3Cl is chloromethane. Hello, reders today we will discuss about what is the intermolecular forces of ch3cl and polarity . I have made this guide to help you out. So, hold your seat and be with the end of guide. (a) CO2 dipole-dipole interactions hydrogen bonding interactions ion-dipole interactions London dispersion forces (b) CHCl3 dipole-dipole interactions hydrogen bonding interactions ion-dipole interactions London Is 2, What is dipole dipole force negative SideIs SiF4 Polar/non polar so I know What they like! Hydrogen bonds form when you have a negative O, N, or F atom in one molecule and a positive H atom attached to an O, N, or F atom in another molecule. See Chloroform How do functional groups affect intermolecular attractions? SO2 and CHCl3 experience dipole-dipole intermolecular forces. a. BCl3 b. H2O c. N2. Discussion - SiF4, geometry tetrahedral, Si-F bonds are polar, but no molecular dipole; bond dipoles cancel. solubility. Dipole forces and London forces are present as intermolecular No dipole-dipole interactions. Ethanol (\(\ce{C2H5OH}\), molar mass 46) boils at 351 K, but water (\(\ce{H2O}\), molar mass 18) boils at higher temperature, 373 K. This is because: water has stronger London dispersion forces. Webch_10_practice_test_liquids_solids-and-answers-combo - Read online for free. Forces binding atoms in a molecule are due to chemical bonding. These are polar forces, intermolecular forces of attraction therefore, dipole-dipole and dispersion forces (always present) What is the intermolecular forces of Which has a higher boiling point, \(\ce{I2}\) or \(\ce{Br2}\)? What is the strongest intermolecular force in CHCl3? In CH3Cl, the C-Cl bond is polar. What intermolecular forces are present in #CO_2#? being in the center. Predict the properties of a substance based on the dominant intermolecular force. 0000001036 00000 n Which of the following molecules have a permanent dipole moment? The intermolecular forces operating in NO would be dipole WebThe molecular mass of CHCl3 is 119.38 amu. The forces holding molecules together are generally called intermolecular forces. Explain properties of material in terms of type of intermolecular forces. Identify type of the intermolecular forces in the following compound. Discussion - Atomic weights for \(\ce{Br}\) and \(\ce{I}\) are 80 and 127 respectively. WebA liquid with weak intermolecular forces evaporates more easily and has a high vapor pressure. (a) In which of the two are the intermolecular forces the weakest? <<756da9636b8db4449f174ff241673d55>]>> We reviewed their content and use your feedback to keep the quality high.
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